Table of IR Absorptions
Functional Group |
Characteristic Absorption(s) (cm-1) |
Notes |
Alkyl C-H Stretch | 2950 - 2850 (m or s) |
Alkane C-H bonds are fairly ubiquitous and therefore usually less useful in determining structure. |
Alkenyl C-H Stretch Alkenyl C=C Stretch |
3100 - 3010 (m) 1680 - 1620 (v) |
Absorption peaks above 3000 cm-1 are frequently diagnostic of unsaturation |
Alkynyl C-H Stretch Alkynyl C=C Stretch |
~3300 (s) 2260 - 2100 (v) |
|
Aromatic C-H Stretch Aromatic C-H Bending Aromatic C=C Bending |
~3030 (v) 860 - 680 (s) 1700 - 1500 (m,m) |
|
Alcohol/Phenol O-H Stretch |
3550 - 3200 (broad, s) |
See "Free vs. Hyrdogen-Bonded Hydroxyl Groups" in the Introduction to IR Spectra for more information |
Carboxylic Acid O-H Stretch |
3000 - 2500 (broad, v) |
|
Amine N-H Stretch |
3500 - 3300 (m) |
Primary amines produce two N-H stretch absorptions, secondary amides only one, and tetriary none. |
Nitrile C=N Stretch |
2260 - 2220 (m) |
|
Aldehyde C=O Stretch
Ketone C=O Stretch
Ester C=O Stretch
Carboxylic Acid C=O Stretch
Amide C=O Stretch |
1740 - 1690 (s)
1750 - 1680 (s)
1750 - 1735 (s)
1780 - 1710 (s)
1690 - 1630 (s) |
The carbonyl stretching absorption is one of the strongest IR absorptions, and is very useful in structure determination as one can determine both the number of carbonyl groups (assuming peaks do not overlap) but also an estimation of which types. |
Amide N-H Stretch |
3700 - 3500 (m) |
As with amines, an amide produces zero to two N-H absorptions depending on its type. |